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  • SYNTHESIS OF EPINEPHRINE

    August 7, 2024
    Amino Acid Metabolism

    Phenylalanine is converted into tyrosine, which is further converted into DOPA by tyrosine hydroxylase with tetrahydropteridine as cofactor. DOPA is decarboxylated to dopamine by a decarboxylase, which is present in many tissues, including a drenal medulla with pyridoxal phosphate as cofactor. The hydroxylation of dopamine is carried out by dopamine β-hydroxylase to form norepinephrine in…

  • KINETICS OF DRUG PERMEATION

    August 7, 2024
    Semisolid Dosage Forms

    Skin can act as a barrier and prevent deep penetration of drug molecules. Percutaneous absorption of most drugs is a passive diffusion process that can be described by Fick’s first law of diffusion. In the initial diffusion stage, drug molecules may penetrate the skin along the hair follicles or sweat ducts and then be absorbed…

  • Titration of amino acids

    August 7, 2024
    Amino Acids

    The existence of different ionic forms of amino acids can be more easily understood by the titration curves as shown in Figure 3.1. At low pH, leucine exists in a fully protonated form as cation. As titration proceeds with NaOH, leucine loses its proton, and at isoelectric pH (pI), it blames a zwitterion. Further titration results…

  • SYNTHESIS OF MELANIN

    August 7, 2024
    Amino Acid Metabolism

    Melanin is the pigment of skin, hair, and eye. The synthesis of melanin occurs in melanosomes present in melanocytes, the pigment-producing cells. Tyrosine is the precursor for melanin and only one enzyme, namely tyrosinase, is involved in its formation. Tyrosinase hydroxylates tyrosine to form 3,4-dihydroxyphenylalanine (DOPA). DOPA can act as a cofactor for tyrosinase. The…

  • MECHANISM OF PERCUTANEOUS DRUG ABSORPTION

    August 7, 2024
    Semisolid Dosage Forms

    On topical application of a semisolid drug, the drug diffuses passively out of its vehicle and partitions into either the stratum corneum or the sebum-filled ducts of the pilosebaceous glands. Inward diffusive movements continue from these locations to the viable epidermal and dermal points of entry. Thus, a concentration gradient develops across the skin up…

  • Isoelectric pH

    August 7, 2024
    Amino Acids

    Isoelectric point (pI) is defined as the pH at which a molecule exists as zwitterion or dipolar ion and carries no net charge. Example: pI for leucine is 6.

  • Physical Properties

    August 7, 2024
    Amino Acids

  • INTRODUCTION

    August 7, 2024
    Semisolid Dosage Forms

    Learning Objectives Semisolid dosage forms are mainly meant for external application on the skin or mucous membrane. They are traditionally used for treating topical ailments. They are also used for treating ophthalmic, nasal, buccal, rectal and vaginal ailments. Semisolid dosage forms may be used for therapeutic, cosmetic or protective properties. Examples are ointments, pastes, creams,…

  • DEGRADATION OF TYROSINE

    August 7, 2024
    Amino Acid Metabolism

    As phenylalanine is converted to tyrosine, a single pathway is responsible for the degradation of both these amino acids, which occurs mostly in liver. In a sequence of reactions, tyrosine is converted to fumarate and acetoacetate. Tyrosine first undergoes transamination to 5-p-hydroxyphenyl pyruvate. P-hydroxyphenyl pyruvate dioxygenase is a copper-containing enzyme. It catalyses oxidative decarboxylation as…

  • PROPERTIES OF AMINO ACIDS

    August 7, 2024
    Amino Acids

    The amino acids differ in their physical chemical properties, which ultimately determine the characteristics of proteins.

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